Ukraine. Ukraine is a country in Eastern Europe. It is the second-largest European country after Russia, which borders it to the east and northeast. It also borders Belarus to the north; Poland and Slovakia to the west; Hungary, Romania and Moldova to the southwest; with a coastline along the Black Sea and the Sea of Azov to the south and southeast. Kyiv is the nation's capital and largest city, followed by Kharkiv, Dnipro, and Odesa. Ukraine's official language is Ukrainian. During the Middle Ages, Ukraine was the site of early Slavic expansion and the area later became a key centre of East Slavic culture under the state of Kievan Rus', which emerged in the 9th century. The state eventually disintegrated into rival regional powers and was destroyed by the Mongol invasions of the 13th century. The area was then contested, divided, and ruled by a variety of external powers for the next 600 years, including the Polish???Lithuanian Commonwealth, the Austrian...